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IntroductionAiming at the effective removals of series of N-containing waste gases, including (NOx, N2O, NH3, RCN) from industry, as well as classical indoor pollutants, such as formaldehyde and ozone; the related mechanisms on high selective transformation of these harmful compounds towards the target unharmful products were studied by means of both experimental DRIFTs & TPD techniques and theoretical DFT calculation to clarify the structure-performance correlation for better design of catalytic materials. Firstly, Cu-SSZ-13 was successfully synthesized by using a relatively cheap & new template of Choline Chloride, achieving an extraordinary deNOx performance with NO conversion of 95% across a broad temperature window of 150-450oC. Secondly, for the purification of N2O-containing exhaust from the industrial plant for adipic acid production with an annual yield of 250,000 tons, granular β-type zeolite catalyst was scale-up prepared based on the design of active sites via molecular simulation and thereafter utilized to reduce the N2O green-house gas of 20,000 tons per year. Thirdly, one-step technique on selective catalytic combustion of acrylonitrile was developed as well as an industrial system was established to eliminate the effluent nitrile gases with a total flow rate of 100,000 m3/h as a chair of National High-Technique Project (863 project). More than 150 academic papers were published in the international journals including Chemical Reviews, National Science Reviews, Environmental Science & Technology, Applied Catalysis B: Environmental, Journal of Catalysis, Journal of Martials Chemistry A etc., associated with one Chinese book, three English book chapters and 30 authorized patents (including 2 US patents). EducationWork ExperienceSocial PositionSocial ActivitiesResearchSeries of classical indoor pollutants and industrially harmful N-containing gases were catalytic elimination by applicant with consideration on both the academic research and the practical application: 1. Principle on the design of highly efficient catalysts for indoor HCHO purification at ambient temperature Almost 90% daily life of human being was spent in room, while indoor formaldehyde can cause the respiratory diseases, teratogenesis, and cancer. Therefore, its purification is essentially meaningful. Aiming at an efficient removal of formaldehyde at room temperature and well use of precious metals as active components, ZSM-5 zeolite with high specific surface area was introduced as ideal support for the noble-metal dispersion. The Pt loading was successfully reduced from 1% to 0.3% along with a complete HCHO conversion at 25 oC due to isomorphic framework substitution by Ti, hydrophobicity modification, NaBH4 surface pretreatment etc. Moreover, 0.2% of Pd was mainly confined in 5-membered rings of ZSM-5 based on an encapsulation strategy. The principle on the selection of coordinative ligands of precious metals is clarified for well dispersion of active component and room-temperature elimination of formaldehyde. Furthermore, Co/NC with an ideal performance was derived from ZIF-67 pyrolysis. Thereafter, Co-N2 was verified as active center for rapid HCHO conversion according to EXAFS characterization and DFT calculation. As a result, transition metal was indeed used as effective candidate for HCHO purification at room temperature, which once puzzled the researcher. 2. Mechanism study on N2O direct decomposition based on both experimental and theoretical approaches Huge amount of N2O, one kind of green-house gases, could be released during the traditional production of adipic acid. The simplest and economic way to deal with this pollutant is the directly catalytic decomposition of N2O into N2 and O2. An “oxygen intermediate” mechanism was proposed via in-situ DRIFT and TPD techniques. Molecular simulation based on DFT calculation was also introduced to confirm the proposed mechanism as well as clarify the correlation between catalyst structure and catalytic performance for a further improvement on industrial catalyst. 2.5 tons of granular Fe-β zeolite catalyst were manufactured and utilized in a tail-gas control system with a gas flow rate of 16,000 m3/h, for an industrial plant yielding adipic acid of 260,000 tons per year. 20,000 tons of N2O was accordingly reduced annually due to this application. This achievement is therefore highly evaluated by <China Paper of Chemical Engineering>. In addition, aiming at satisfactory purification of the exhaust gases containing N2O from caprolactam production, a pilot test was conducted with a flow rate of 40 m3/h for Hengyi Corporation in Zhejiang Province. Synergistic elimination of N2O, ammonia, and tert-butyl alcohol was achieved based on a catalyst-combination strategy. 3. Academic basis on the engineering application of selective catalytic combustion of highly toxic nitrile gases Nitrile gases including acrylonitrile, acetonitrile, and HCN coming from chemical process are known to be highly toxic and danger. A novel technology of selective catalytic combustion over Cu-ZSM-5 with SiO2/Al2O3=30 as a catalyst was developed by the applicant, showing an idea efficiency for nitrile conversion and N2 yield as high as 95%. The serious problem on the substrate cracking during dry process on construction of honeycomb zeolite monolith for the practical application was well solved. An industrial post-treatment system was established loading with 5 m3 of zeolite monolith for purifying the effluent gases with a flow rate of 100,000 m3/h from acrylonitrile plant of Jilin Corporation, SINOPEC. Moreover, the process package for purification of exhaust gases from carbon fiber production in Shanghai Corporation, SINOPEC, was accomplished with the corresponding post-treatment system being simultaneously established with a comprehensive consideration on sampling device design, tar removal, quantitative/qualitative analysis on the multiple pollutants in exhaust. Teaching<Cause and Control Technology of Air Pollution>, Core course for undergraduate students, 36 hours <Industrial Catalysis> (fully in English), Core course for graduate students, 48 hours <Brief introduction on new materials and technologies with the “Carbon Peak & Carbon Neutralization” background in China>, General course for graduate students, 6 hours <Industrial Chemistry>, Specialized course for undergraduate students, 6 hours <Air Pollution Catalytic Control>, Specialized course for undergraduate students, 3 hours PostgraduatesFunding1. Design on zeolite catalysts for highly selective combustion to N2 of acrylonitrile from petrochemical industry (U1862102), 420,000 yuan, 2018-2021, National Natural Science Foundation of China 2. Principle on the core-shell structural construction of zeolite catalysts for highly efficient removal of NOx (21976012), 660,000 yuan, 2020-2023, National Natural Science Foundation of China 3. Encapsulation of precious metals by zeolite for highly effective removal of formaldehyde at room temperature, (22176010), 600,000 yuan, 2021-2025, National Natural Science Foundation of China 4. System establishment and catalytic technique on purifying the low-concentration nitrile-containing exhaust gases from carbon fiber production (H2021292), 2,900,000 yuan, 2021-2024, SINOPEC Research & Development Founding 5. Single-atom catalysis related to environmental or energy field (XK1802-1), 4,000,000 yuan, 2017-2022, Key Program on the “Double First Class” Discipline Construction, Ministry of Education. 6. Green technology for the isocyanate production with a source substitution of highly toxic phosgene feed (2023YF3905404), 70,000 yuan, 2024-2027, Key R & D Program, Ministry of Science and Technology. Vertical ProjectHorizontal ProjectPublicationsBook: 1. R. Zhang, P. Li, H. Wang. “Catalytic Abatement of NOx Emissions over the Zeolite Catalysts” Chapter III VIII in <Heterogeneous Catalysts: Emerging Techniques for Design, Characterization and Applications>, Wiley-VCH Publishers, Inc., Germany, ISBN 978-3-527-34415, 2021, Pages 685-698. 2. R. Zhang, B. Chen. “Air Pollution Catalytic Control by Metal Promoted Zeolites” as Chapter II in <Zeolite synthesis, chemistry and applications>, Nova Science Publishers, Inc., New York, USA, ISBN 978-1-61942-861-4, 2012, Pages 55-92. 3. R. Zhang and S. Kaliaguine, “Application of Perovskite for Automobile Exhaust Purification” as Chapter I in <Heterogeneous Catalysis Research Progress>, Nova Science Publishers, Inc., New York, USA, ISBN 978-1-60456-979-7, 2008, Pages 1-79. Review: 1. R. Zhang, N. Liu, B. Chen*, Z. Lei, Selective transformation of various nitrogen-containing exhaust gases towards N2 over the zeolite-based catalysts, Chem. Rev., 116 (2016) 3658-3721. (IF=60.622) Cover Review 2. Xuanhao Wu, Jiaxin Du, Yanxia Gao, Haiqiang Wang, Changbin Zhang, Runduo Zhang*, Hong He*, Gaoqing (Max) Lu*, and Zhongbiao Wu*, Progress and Challenges on Nitrous Oxide Decomposition and Valorization, 2024, Chem. Soc. Rev., minor revision. 3. Y. Shan, J. Du, Y. Zhang, W. Shan, X. Shi, Y. Yu, R. Zhang, X. Meng, F. Xiao, H. He*, Selective catalytic reduction of NOx with NH3: opportunities and challenges of Cu-based small-pore zeolites, National Sci. Rev. 8 (2021) nwab010. (IF=17.275) Selected Academic Paper: 1. Bin Kang, Mengfei Guo, Haotian Wu, Xiaonan Guo, Zhaoying Di, Ying Wei, Jingbo Jia, Zhou-jun Wang, Runduo Zhang*, Effect of alkali/alkaline-earth-metal doping on Co3O4 spinel structure and N2O decomposition, Catalysis Science & Technology, 2024, http://doi.org/10.1039/D4CY00400K. 2. Xiaonan Guo, Runduo Zhang*, Zhaoying Di, Bin Kang, Ying Wei, Jingbo Jia, Rational design on hierarchically porous Cu/ZSM-5 zeolite for promoting low-temperature NH3-SCR performance based on protectively alkali-etching strategy, Catalysis Today, 2024,433 (2024) 114656. 3. Leping Cheng, Yuwei Liu, Die Li, Wenjie Xu, Jingbo Jia*, Runduo Zhang, Ying Wei, Maria A. Goula, Vogelis G. Papadakis, Coupling pyrolysis and catalytic reforming of waste plastics for syngad production over confined Ni within slicalite-1 catalysts, International Journal of Hydrogen Energy, 69 (2024) 381-390. 4. Chao Feng*, Chong Chen, Jun Wang, Shuangju Li, Fang Liu, Yuan Pan, Yukun Lu, Yuanshuai Liu, Xuebing Li, Yunqi Liu, Runduo Zhang, Zhong Wang*, Insights into the synergistic effect and catalytic mechanism in MnCeOx solid solution catalysts for low-temperature propane total oxidation, Surface and Interfaces, 46 (2024) 104011. 5. Shaohua Du, Bin Kang, Xiaonan Guo, Ying Wei, Jingbo Jia*, Runduo Zhang*, Catalytic reduction of N2O by NH3 over Fe-zeolite catalysts with different topologies, Catalysis Letters, (2024).https://doi.org/10.1007/s10562-024-04637-7 6. Chao Feng*, Yuxi Bi, Chong Chen, Yunxia Wang, Shuangju Li, Yuan Pan, Hongchuan Xin, Yukun Lu, Fang Liu, Xuebing Li, Yunqi Liu, Runduo Zhang, Zhong Wang*, Construction of Pd/Mn3O4 heterojunction catalyst for efficient photothermal synergetic catalytic propane total oxidation, Sep. Purif. Technol.,336 (2024) 126255. 7. Hanxiao Shen, Kun Wang, Zhaoying Di, Xiaonan Guo, Bin Kang, Runduo Zhang*, Jingbo Jia, Ying Wei, Efficient decomposition of ozone at room temperature by cobalt-organic ZIF-67 nanostructure and its derivatives, ACS Appl. Nano Mater., 7:1 (2023) 606-617. 8. Yanru Zhu, Shaowei Guo, Najie Zhuang, Qi Ping, Jian Zhang, Zhe An, Hongyan Song, Xin Shu, Wei Xi, Lirong Zheng, Runduo Zhang, and Jing He*, High-density dispersion of atomic Pt (Ru, Rh, Pd, Ir) induced by meso-stable penta-coordinated FeIII in the topological transformation of layered double hydroxides, ACS Catal., 14:1 (2024) 56-66. 9. H. Li, X. Hou, L. Zhang, Y. Wei*, Y. Kiang, J. Qiao, H. Su, X. Gao. J. Jia. R. Zhang, Alkyl-imidazolium templating synthesis to extra-large-pore alaminogermanosilicate zeolite IRR with enhanced Al substitution and excellent catalytic performance in bulky molecule acetalization, Journal of Porous Materials, 30:4 (2023) 1311-1318. (IF=2.6) 10. Guiming Xie, Xingyang Bai, Yi Man, Pengju Ren, Rongrong Jin, Runduo Zhang, Kostya (Ken) Ostrikov, Zhou-jun Wang,* Qingyuan Yang,*High-performance Al-doped Cu/ZnO catalysts for CO2 hydrogenation to methanol: MIL-53(Al) source-enabled oxygen vacancy engineering and related promoting mechanisms, Chemical Engineering Journal, 480 (2024) 148195 11. Xiaonan Guo, Runduo Zhang*, Zhaoying Di, Bin Kang, Hanxiao Shen, Ying Wei, Jingbo Jia, Lirong Zheng, Outstanding low-temperature performance for NH3-SCR of NO over broad Cu-ZSM-5 sheet with highly exposed a-c orientation, Appl. Catal. B: Environ., 343 (2024) 123519. (IF=22.1) 12. Yan Liang, Ying Wei,* Haojie Li, Junjun Qiao, Jingbo Jia, Ningning Gao,* Ling Zhang, Runduo Zhang, Dry-gel direct conversion to silico-aluminophosphate zeotype with LTA Structure, Chemical Letters, 2023, 52, 654–657. 13. 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Liu, Economical way to synthesize SSZ-13 with abundant ion-exchanged Cu+ for an extraordinary performance in selective catalytic reduction (SCR) of NOx by ammonia, Environ. Sci. Technol., 48 (2014) 13909-13916. (IF=9.028) 76. R. Zhang, P. Li, N. Liu, W. Yue, B. Chen*, Effect of hard-template residues of the nanocasted mesoporous LaFeO3with extremely high surface areas on catalytic behaviors for methyl chloride oxidation, J. Mater. Chem. A, 2 (2014) 17329-17340. (IF=12.732) Cover Paper 77. W. Yue, R. Zhang*, N. Liu, B. Chen, Selective catalytic oxidation of ammonia to nitrogen over orderly mesoporous CuFe2O4 with high specific surface area, Chin. Sci. Bull., 59 (2014) 3980-3986. (IF=11.78) 78. R. Zhang*, N. Liu, Z. Luo, W. Yang, X. Liang, R. Xu, B. Chen, D. Duprez, S. Royer*, A remarkable catalyst combination to widen the operating temperature window of the selective catalytic reduction of NO by NH3, ChemCatChem, 6 (2014) 2263-2269. (IF=5.686) Cover Paper 79. N. Liu, R. Zhang*, Y. Li, B. Chen, Local electric field effect of TMI (Fe, Co, Cu)-BEA on N2O direct dissociation, J. Phys. Chem. C, 118 (2014) 10944-10956. (IF=4.126) 80. R. Zhang, D. Shi, N. Liu, Y. Cao, B. Chen*. Mesoporous SBA-15 promoted by 3d-transition metal and noble metal ions for selective catalytic combustion of acetonitrile, Appl. Catal. B, 146 (2014) 79-93. (IF=19.503) 81. R. Zhang, W. Yang, N. Luo, P. Li, Z. Lei, B. Chen*. Low-temperature NH3-SCR of NO by lanthanum manganite perovskites: effect of A-/B-site substitution and TiO2/CeO2 support, Appl. Catal. B, 146 (2014) 94-104. (IF=19.503) 82. W. Yang, R. Zhang*, B. Chen, N. Bion, D. Duprez, L. Hou, H. Zhang, S. Royer*. Design of nanocrystalline mixed oxides with improved oxygen mobility: a simple non-aqueous route to nano-LaFeO3 and the consequences on the catalytic oxidation performances, Chem. Commun., 49 (2013) 4923-4925. (IF=5.996) 83. R. Zhang, P. Lei, N. Liu, W. Yang; X. Wang; B. Chen*. CO catalytic combustion over Co/Al2O3: influence of diverse textural properties of alumina supports on the related oxidation activities, Catal. Today, 216 (2013) 169-177. (IF=6.766) 84. R. Zhang, N. Luo, W. Yang, N. Liu, B. Chen*. Low-temperature selective catalytic reduction of NO with NH3 using perovskite-type oxides as the novel catalysts, J. Mol. Catal. A: Chem., 371 (2013) 86-93. (IF=4.211) 85. C. Dai, Z. Lei*, Y. Wang, R. Zhang, B. Chen, Reaction of N2O by CO over Fe and Cu-BEA zeolites: An experimental and computation al study of the mechanism, Micropor. Mesopor. Mat., 167 (2013) 254-266. (IF=5.455) 86. C. Dai, Z. Lei*, Y. Wang, R. Zhang, B. Chen, Transfer and reaction performances of selective catalytic reduction of N2O with CO over monolith catalysts, Chin. J. Chem. Eng., 21 (2013) 835-843. (IF=3.171) 87. W. Yang, R. Zhang*, B. Chen, D. Duprez, S. Royer*. New aspects on mechanism of C3H6-SCR of NO in the presence of O2 over LaFe1-x(Cu, Pd)xO3-δ perovskites, Environ. Sci. 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Sun, Study on the direct decomposition of nitrous oxide over Fe-beta zeolites: from experiment to theory, Catal. Today, 175 (2011) 245-255. (IF=6.766) 93. N. Liu, B. Chen, Y. Li, R. Zhang*, X. Liang, Y. Li, Z. Lei. Charge transfer analysis on the direct decomposition of nitrous oxide over Fe-BEA zeolites: an experimental and density functional study, J. Phys. Chem. C, 115 (2011) 12883-12890. (IF=4.126) 94. J. Xiao, B. Chen, X. Liang*, R. Zhang. Y. Li, NiO microspheres with tunable porosity and morphology effects for CO oxidation, Catal. Sci. Technol., 1 (2011), 999-1005. (IF=6.119) 95. R. Zhang*, W. Teoh, R. Amal, B. Chen, S. Kaliaguine*, Selective catalytic reduction of NO by CO over Cu/Ce1-xZrxO2 prepared by flame synthesis, J. Catal., 272 (2010) 210-219. (IF=7.92) 96. R. Zhang*, N. Luo, B. Chen* and S. Kaliaguine, Soot combustion over lanthanum cobaltites and related oxides for diesel exhaust treatment, Energ. Fuel., 24 (2010) 3719-3726. (IF=3.605) 97. Y. Wang, Z. Lei*, R. Zhang, B. Chen, Adsorption of NO and N2O on Cu-BEA zeolite, J. Mol. Struc.: THEOCHEM, 957 (2010) 41-46. (IF=2.463) 98. R. Zhang*, W. Yang, J. Xue, B. Chen*, The influence of O2, hydrocarbons, CO, H2, NOx, SO2, and water vapor molecules on soot combustion over LaCoO3 perovskite, Catal. Lett., 132 (2009) 10-15. (IF=3.186) 99. R. Zhang*, W. Yang, J. Xue, B. Chen*, Role of structural deficiency of nanoscaled perovskites prepared by reactive grinding on the catalytic purification of exhaust pollutants, Int. J. Chem. React. Eng., 7 (2009) A49. (IF=1.51) 100. J. Li, J. Zhang*, R. Zhang, W. Cao, Study on nanosized Cobalt-based catalyst prepared by supercritical phase condition for Fischer-Tropsch synthesis, J. Nat. Gas Chem., 18 (2009) 325-330. (IF=7.216) 101. Z. Tan, H. Xiao*, R. Zhang, Z. Zhang, S. Kaliaguine, Potential to use mesoporous carbon as catalyst support for hydrodesulfurization, New Carbon Mater., 24 (2009) 333-343. (IF=1.905) 102. R. Zhang, H. Alamdari, S. Kaliaguine*, SO2 poisoning of LaFe0.8Cu0.2O3 perovskite prepared by reactive grinding during NO reduction by C3H6, Appl. Catal. A: Gen., 341 (2008) 140-151. (IF=5.706) 103. R. Zhang, H. Alamdari, M. Bassir, S. Kaliaguine*, Crystal structure, redox properties and catalytic performance of Ga-based mixed oxides for NO reduction by C3H6, Catal. Commun., 9 (2008) 111-116. (IF=3.626) 104. R. Zhang*, S. Kaliaguine, The lean reduction of NO by C3H6 over Ag/alumina derived from Al2O3, AlOOH and Al(OH)3, Appl. Catal. B: Environ., 78 (2008) 275-287. (IF=19.503) 105. R. Zhang, H. Alamdari, S. Kaliaguine*, Water vapor sensitivity of nanosized La(Co, Mn, Fe)1-x(Cu, Pd)xO3 perovskites during NO reduction by C3H6 in the presence of oxygen, Appl. Catal. B: Environ., 72 (2007) 331-341. (IF=19.503) 106. R. Zhang, H. Alamdari, S. Kaliaguine*, Catalytic conversion of NO and C3H6 over silver catalysts under stoichiometric or excess oxygen, Catal. Lett., 119 (2007) 108-119. (IF=3.186) 107. R. Zhang, H. Alamdari, S. Kaliaguine*, Optimization of mixed catalysts for catalytic conversion of NO and C3H6 in lean burn conditions, Int. J. Chem. React. Eng., 5 (2007) A70. (IF=1.51) 108. R. Zhang, A. Villanueva, H. Alamdari, S. Kaliaguine*, Cu- and Pd- substituted nanoscale Fe-based perovskites for selective catalytic reduction of NO by propene, J. Catal., 237 (2006) 368-380. (IF=7.92) 109. R. Zhang, A. Villanueva, H. Alamdari, S. Kaliaguine*, Catalytic reduction of NO by propene over LaCo1-xCuxO3 perovskites synthesized by reactive grinding, Appl. Catal. B: Environ., 64 (2006) 220-233. (IF=19.503) 110. R. Zhang, A. Villanueva, H. Alamdari, S. Kaliaguine*, SCR of NO by propene over nanoscale LaMn1-xCuxO3 perovskites, Appl. Catal. A: Gen., 307 (2006) 85-97. (IF=5.706) 111. R. Zhang, A. Villanueva, H. Alamdari, S. Kaliaguine*, Reduction of NO by CO over nanoscale LaCo1-xCuxO3 perovskites, J. Mol. Catal. A: Chem., 258 (2006) 22-34. (IF=4.211) 112. R. Zhang, H. Alamdari, S. Kaliaguine*, Fe-based perovskites substituted by copper and palladium for NO + CO reaction, J. Catal., 242 (2006) 241-253. (IF=7.92) 113. R. Zhang, H. He*, X. Shi, C. Zhang, B. He, J. Wang, Preparation and emission characteristics of ethanol-diesel fuel blends, J. Environ. Sci., 16 (2004) 793-796. (IF=5.565) AwardsIn 2009, the applicant was entitled as New Century Excellent Talent of Ministry of Education. In 2014, the applicant won the Natural Science Award (second class) of Ministry of Education. In 2016, the applicant established the Beijing Key Laboratory of Energy Environmental Catalysis and accordingly served as the director. In 2022, the applicant was ranked as World’s Top 2% Scientists based on Elsevier Scopus database. PatentHonor RewardAdmissions Information |