Yang zhiyu

Representative works(4):

1.High Flux and Stability of Cationic Intercalation in Transition Metal Oxides: Unleashing the  Potential of Mn t2g Orbital via Enhanced π-Donation. J. Am. Chem. Soc. 2023, 145, 49, 26699-26710.  

Representative works in Past 3 years

[1] Adjusting the Coordination Environment of Mn Enhances Supercapacitor Performance of MnO2 Anqi Zhang, Rui Zhao, Lingyuan Hu, Ru Yang, Shuyun Yao, Shiyu Wang, Zhiyu Yang,* and Yi-Ming Yan* Adv. Energy Mater. 2021, 11, 2101412.

[2]Delocalizing the d-electrons Spin States of Mn Site in MnO2 for Anion-Intercalation Energy Storage. Shuyun Yao, Shiyu Wang, Ruochen Liu, Xia Liu, Zhenzhen Fu, Dewei Wang, Haigang Hao,* Zhiyu Yang,* Yi-Ming Yan*. Nano Energy 2022, 107391.

[3] Stabilization of Cu+ via Strong Electronic Interaction for Selective and Stable CO2 Electroreduction. Yixiang Zhou, Yebo Yao, Rui Zhao, Xiaoxuan Wang, Zhenzhen Fu, Dewei Wang, Huaizhi Wang, Liang Zhao, Wei Ni, Zhiyu Yang,* Yi-Ming Yan* Angew. Chem. Int. Ed. 2022, 61, 2205832.

[4] Interfacial electric field triggered N2 activation for efficient electrochemical synthesis of ammonia, Xiaoxuan Wang, Xinyue Chi, Zhenzhen Fu, Yuanyuan Xiong, Shuyuan Li, Yebo Yao, Kaixin Zhang, Yongjia Li, Shiyu  Wang, Rui Zhao, Zhiyu Yang, Yi-Ming Yan; Applied Catalysis B: Environmental 2023, 322, 122130.

[5] Internal Electric Field Induced by Superexchange Interaction on Mn4+-O2−-Ni2+ Unit Enables Highly Efficient Hybrid Capacitive Deionization. Dewei Wang, Zhenzhen Fu, Xia Liu, Yebo Yao, Yingjie Ji, Xueying Gao, Jinrui Wang, Zishan Hou, Yongjia Li, Shuyun Yao, Shiyu Wang, Jiangzhou Xie, Zhiyu Yang*, Yi-Ming Yan Small 2023, 19, 36, 2301717.

[6] Optimizing Electrocatalytic Nitrogen Reduction via Interfacial Electric Field Modulation: Elevating d-Band Center in WS2-WO3 for Enhanced Intermediate Adsorption. Xiaoxuan Wang, Shuyuan Li, Zhi Yuan, Yanfei Sun, Zheng Tang, Huiying Zhang, Jingxian Li, Shiyu Wang, Dongchun Yang, Jiangzhou Xie*, Zhiyu Yang*, Yi-Ming Yan* Angew. Chem. Int. Ed. 2023,62, e202303794.

[7] Boosting CO2 Electroreduction to C2H4 via Unconventional Hybridization: High-Order Ce4+ 4f and O 2p Interaction in Ce-Cu2O for Stabilizing Cu+. Sun, Yanfei; Xie, Jiangzhou; Fu, Zhenzhen; Zhang, Huiying; Yao, Yebo; Zhou, Yixiang; Wang, Xiaoxuan; Wang, Shiyu; Gao, Xueying; Tang, Zheng; Li, Shuyuan; Wang, Xiaojun; Nie, Kaiqi; Yang, Zhiyu *; Yan, Yiming* ACS Nano 2023, 17, 14, 13974-13984.

[8] Local Electric Field Induced by Atomic-Level Donor–Acceptor Couple of O Vacancies and Mn Atoms Enables Efficient Hybrid Capacitive Deionization

Zhenzhen Fu, Dewei Wang, Yebo Yao, Xueying Gao, Xia Liu, Shiyu Wang, Shuyun Yao, Xiaoxuan Wang, Xinyue Chi, Kaixin Zhang, Yuanyuan Xiong, Jinrui Wang, Zishan Hou, Zhiyu Yang, Yi-Ming Yan* Small, 2023,19, 2205666.

[9] Elevating the Orbital Energy Level of dxy in MnO6 via d–π Conjugation Enables Exceptional Sodium-Storage Performance. Xia Liu, Yebo Yao, Dewei Wang, Shuyun Yao, Shiyu Wang, Zhenzhen Fu, Yongjia Li, Jinrui Wang, Zishan Hou, Xueying Gao, Zhiyu Yang, Yi-Ming Yan. Adv. Energy Mater.2023, 13, 2300384.

[10] Spatially expanded built-in electric field via engineering graded junction enables fast charge transfer in bulk MnO@Mn3O4 for Na+ supercapacitors nano energy. Shiyu Wang, Rui Zhao, Shuyun Yao, Xiaoxuan Wang, Jinrui Wang, Xueying Gao, Zishan Hou, Xia Liu, Zhenzhen Fu, Dewei Wang, Jiangzhou Xie, Zhiyu Yang*, Yi-Ming Yan* Nano Energy 2023, 115, 108725

[11] Enhancing interfacial electric field in WO3-C3N4 through fermi level modulation for electrocatalytic nitrogen reduction. Xiaoxuan Wang; Jiangzhou Xie; Shuyuan Li; Zhi Yuan; Yanfei Sun; Xueying Gao; Zheng Tang; Huiying Zhang; Jingxian Li; Shiyu Wang; Zhiyu Yang*; Yi-Ming Yan* Applied Catalysis B: Environmental 2023, 339, 123126

[12] Boosted N2 Activation through 4f-2p-3d Orbital Hybridization for Efficient Nitrate ElectrosynthesisShuyuan Li, Xiaoxuan Wang, Xinyue Chi, Yuanyuan Xiong, Yanfei Sun, Zheng Tang, Xueying Gao, Huiying Zhang, Jingxian Li, Kaiqi Nie, Jiangzhou Xie, ZhiYu Yang, Yi-Ming Yan Advanced Functional Materials 2023, 33, 49, 2306098https://doi.org/10.1002/adfm.202306098

[13] Interfacial hydrogen spillover on Pd-TiO2 with oxygen vacancies promotes Formate electrooxidation.Zheng Tang, Yongjia Li, Kaixin Zhang, Xiaoxuan Wang, Shiyu Wang, Yanfei Sun, Huiying Zhang, Shuyuan Li, Jinrui Wang, Xueying Gao, Zishan Hou, Lanlan Shi, Zhi Yuan, Kaiqi Nie, Jiangzhou Xie, * Zhiyu Yang, * Yi-Ming Yan* ACS Energy Letter 2023, 8, 9, 3945-3954

https://doi.org/10.1021/acsenergylett.3c01426

[14] Boosted Sodium Ion Storage Performance in MnO2: Understanding the Bond Angle-Mediated Orbital Overlap in MnO6 units for Fast Charge TransferJinrui Wang, Zishan Hou, Xia Liu, Shiyu Wang, Shuyun Yao, Yebo Yao, Dewei Wang, Xueying Gao, Huiying Zhang, Zheng Tang, Yuanming Liu, Kaiqi Nie, Jiangzhou Xie, Zhiyu Yang*, Yi-Ming Yan* Journal of Energy Chemistry2023, 87, 295-303https://doi.org/10.1016/j.jechem.2023.08.044

[15] High Flux and Stability of Cationic Intercalation in Transition Metal Oxides: Unleashing the Potential of Mn t2g Orbital via Enhanced π-Donation. Shuyun Yao, Shiyu Wang, Yuanming Liu, Zishan Hou, Jinrui Wang, Xueying Gao, Yanfei Sun, Weijie Fu, Kaiqi Nie, Jiangzhou Xie,* Zhiyu Yang,* and Yi-Ming Yan* J. Am. Chem. Soc. 2023, 145, 49, 26699-26710. https://doi.org/10.1021/jacs.3c08264

[16] Eliminating the Mn 3d Orbital Degeneracy to Suppress the Jahn-Teller Distortion for Stable MnO2 Cathode. Zishan Hou, Jinrui Wang, Ningning Dai, Shuyun Yao, Shiyu Wang, Yingjie Ji, Xueying Gao, Huiying Zhang, Zheng Tang, Yanfei Sun, Shuyuan Li, Yuanming Liu, Weijie Fu, Kaiqi Nie, Yining Jiang, Yi-Ming Yan, Zhiyu Yang* Adv. Energy Mater. 2023, 2302477.

[17] Deciphering the Stability Mechanism of Cu Active Sites in CO2 Electroreduction via Suppression of Antibonding Orbital Occupancy in the O 2p-Cu 3d Hybridization ACS Catal2024, 14, 3, 1351-1362.

[18] Modulating d-orbital occupancy via a coupled interfacial-local electric field for electrocatalytic N2 fixation.Xiaoxuan Wang, Jiangzhou Xie, Yingjie Ji, Shuyuan Li, Jingxian Li, Shiyu Wang, Yanfei Sun, Xueying Gao, Zheng Tang, Huiying Zhang, Feike Zhang, Zhiyu Yang*, Yi-Ming Yan*. Applied Catalysis B: Environmental2024, 345, 123700.

[19] Engineering Antibonding Orbital Occupancy for Enhanced Sodium-Ion Intercalation Kinetics in Transition Metal Oxides. Jinrui Wang, Zishan Hou, Shiyu Wang, Shuyun Yao, Xueying Gao, Huiying Zhang, Zheng Tang, Yuanming Liu, Kaiqi Nie, Jiangzhou Xie*, Zhiyu Yang*, Yi-Ming Yan*. Advanced Functional Materials, Accept.

[20] Activation of MnO6 Units via an Interfacial Electric Field: Electron Injection into Mn t2g for Rapid and Stable Sodium Ion Storage in CeO2/MnOx.Shuyun Yao, Shiyu Wang, Jinrui Wang, Zishan Hou, Xueying Gao, Yuanming Liu, Weijie Fu, Kaiqi Nie, Jiangzhou Xie, Zhiyu Yang*, Yi-Ming Yan*, Small, Accept.