Liu Dahuan头像

Liu Dahuan
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Fields ： adsorption and separation
Professor 
Department ： College of Chemical Engineering
Degree: PhD
DBLPc:

Introduction

Aiming to the efficient separation of several difficult-to-separate systems, we proposed the research idea of “material design, controlled synthesis and process optimization based on big-data calculation” to carry out systematic research on the difficult-to-separate mixtures, using the concept of molecular chemical engineering. The research was financially supported by the National Natural Science Fund for Excellent Young Scientists. We won Outstanding scientific and technological workers in the national petroleum and chemical industry, the First Prize of Science and Technology Progress Award of China Petroleum and Chemical Industry Federation, the Second Prize of the Beijing Science and Technology Award and the First Prize of the Tianjin Science and Technology Award. More than 170 papers have been published in Top journals in chemistry and chemical engineering, including AIChE J., JACS, Angew. Chem. and Adv. Funct. Mater. 15 Chinese patents have been granted.


Education

Work Experience

Social Position

Social Activities

Research

1. High-Efficiency Adsorptive Separation Technology for Low-Concentration Greenhouse Gases: Driven by the significant demands of the national dual-carbon strategy and energy structure transformation, there are stringent requirements for the emission of greenhouse gases such as CO2 and CH4 (coalbed methane). These gases are often present at low concentrations in various application scenarios and typically contain multiple other components, leading to low separation efficiency, low utilization rates, and high costs with existing materials and technologies. Our research team has developed a series of novel nano-micro structured separation materials with excellent separation selectivity and adsorption capacity, and designed an efficient separation process. This technology offers the advantages of low energy consumption, high recovery rate, high purity, and environmental friendliness, demonstrating significant economic and social benefits.

 

2. High-Efficiency Extraction Materials for Rare Elements from Salt Lakes: We have developed a series of adsorbents capable of efficiently adsorbing borate ions, rubidium, and cesium ions, featuring high adsorption capacity and good stability. These materials can effectively remove trace rare elements from solutions at different stages of the salt lake industry.


Teaching

Principles of Chemical Engineering for undergraduate students.

Postgraduates

Funding

1. Regulating separation performance of gaseous light hydrocarbons through MOFs with local flexibility, NSFC.

2. Development and scalable preparation of alkaline-earth-based adsorbents with low-cost and high-efficiency for oxygen production, National Key R&D Program of China.

3. High-throughput preparation and evaluation methods for membrane materials, National Key R&D Program of China.

4. Efficient Adsorptive Extraction of Rare Elements from Salt Lakes, Natural Science Foundation of Qinghai Province of China.



Vertical Project

Horizontal Project

Publications

1.   Y. Wen, J. Fu, T. Yan, Dahuan Liu*, Combining machine learning and molecular simulation to explore MOF materials that contribute to CF4/N2 separation, Inorg. Chem. Commun., 2024, 168, 112927.

2.   P. Guo, Y. Ying*, Dahuan Liu*, One Scalable and Stable Metal-Organic Framework for Efficient Separation of CH4/N2 Mixture, ACS Appl. Mater. Interfaces, 2024, 16, 7338-7344.

3.    T. Wang, J. Fu, X. Gao, G. Li, Dahuan Liu*, Pore engineering of MOF-808 for effective adsorption of roxarsone, Sep. Purif. Technol., 2024, 348, 127724.

4.       C. Guo, P. Guo, Y. Zhou, X. Yan, H. Li, Dahuan Liu*, A Core-shell IL@MOF Composite with Ultra-high Selectivity in Multiple CO2 Purification Systems, Chem. Eng. Sci., 2024, 292, 119983.

5.   T. Wang, J. Fu, W. Zhang, Dahuan Liu*, Construction of defective hydroxyl-rich metal-organic framework for effective capture of borate ion, Chem. Eng. J., 2024, 483, 149023.

6.       文一如，付佳，刘大欢*。 基于机器学习的MOFs材料研究进展：能源气体吸附分离. 化工学报,  2023，DOI: ‪10.11949/‪0438-1157.20231381.

7.       M. Chang, C. Yang, M. Tong, J. Yang, T. Ma, S. Jiao, Q. Ma, Y. Wang, Dahuan Liu*, J. Zheng, A Robust Al-Based Metal-Organic Framework for Highly Efficient Natural Gas Purification, Ind. Eng. Chem. Res., 2024, 63, 2851-2860.

8.    J. Fu, Z.-J. Wang, Dahuan Liu*, Mechanistic Insight into the Direct Nonoxidative Conversion of Methane to Ethylene over Structure-Sensitive RhO2/TiO2 Catalysts, J. Phys. Chem. C, 2023, 127(46), 22557-22569.

9.     B. Xue, C. Yang, M. Chang, Dahuan Liu*, Structural design of core-shell ZIF-8@NH2-MIL-125 photocatalyst for synergistic adsorption-photocatalytic degradation of tetracycline hydrochloride, J. Alloys Compd., 2024, 973, 172850.

10.   M. Chang, J. Ren, Y. Wei, T. Yan, J.-X. Wang*, Dahuan Liu*, J.-F. Chen, Discovery of a Scalable Metal-Organic Framework with a Switchable Structure for Efficient CH4/N2 Separation, Chem. Mater., 2023, 35(11), 4286–4296.

11.    X. Zhao, L. Zhang, B. Liu*, C. Zhang, H. Zhao, C.-C. Wang*, Dahuan Liu*, Recycling of stainless steel pickling wastewater and polyethylene terephthalate plastic: A total-waste synthesis of metal-organic framework, Progress in Natural Science: Materials International, 2023, 33, 478-485.

12.    Y. Wei, M. Chang, L.-X. Yun, M. Qiao, R.-K. Liu, Dahuan Liu*, J.-X. Wang*, J.-F. Chen, Greatly intensified guest exchange strategy for highly-efficient activation of metal-organic frameworks, Small, 2023, 2303848.

13.    T. Yan, M. Tong*, Dahuan Liu*, Q. Yang*, C. Zhong, Machine Learning Assisted Computational Exploration of the Optimal Loading of IL in IL/COF Composites for Carbon Dioxide Capture, J. Mater. Chem. A,2023, 11, 14911-14920.

14.   P. Guo, Y. Ying*, M. Chang, Dahuan Liu*, One ethane-selective metal-organic framework with customized pore size and specific binding sites for efficient purification of ethylene, Sep. Purif. Technol., 2023, 323, 124465.

15.    T. Wang, H. Zhao, X. Zhao*, Dahuan Liu*, Construction of defective zirconium-based metal–organic frameworks for enhanced removal of toxic selenite: performance and mechanism studies, J. Colloid Interface Sci., 2023, 647, 488-498.

16.   H. Li, Y. Li, X. Yang, Dahuan Liu*, X. Liu*, Synergy of charge capture and transfer by Ni-MOF nanosheets for enhancing energy storage performance of polyetherimide-based dielectric nanocomposites, Appl. Phys. Lett.,2023, 122, 202903.

17.  J. Yang, M. Tong*, G. Han, M. Chang, T. Yan, Y. Ying, Q. Yang, Dahuan Liu*, Solubility-Boosted Molecular Sieving-Based Separation for Purification of Acetylene in Core-Shell IL@MOF Composites, Adv. Funct. Mater., 2023, 33, 2213743.

18.    T. Zhang, S. Lin, T. Yan, B. Li, Y. Liang, Dahuan Liu*, Y. He*, Integrating Self-Partitioned Pore Space and Amine Functionality into an Aromatic-Rich Coordination Framework with Ph Stability for Effective Purification of C2 Hydrocarbons, Inorg. Chem., 2023, 62, 5593–5601.

19.    Z. Wan, T. Yan, M. Chang, M. Yang, Dahuan Liu*, Nickel-Based Metal−Organic Framework for Efficient Capture of CF4 with a High CF4/N2 Selectivity, Sep. Purif. Technol., 2023, 306, 122617.

20.    H. Zhao, T. Wang, Dahuan Liu*, Q. Yang*, Recovery of syringic acid from aqueous solution by magnetic Fe-Zn/ZIF and its slow-release from CA-coating carrier based on a 3Rs concept, CrystEngComm, 2022, 24, 8427-8433.

21.    Y.-J. Zhao, W.-Q. Tang, X.-W. Wang, H.-F. Zhao, Z.-Y. Gu, Q. Yang, Dahuan Liu*, Isomers recognition by dynamic guest-adaptive ligand rotation in a metal-organic framework with local flexibility, Chem. Sci., 2022, 13, 11896-11903.

22.   H. Zhao, X. Gu, T. Yan, G. Han*, Dahuan Liu*,A novel IL/MOF nanocomposite tailored for trace SO2 efficient capture based on synergistic effects, AIChE J., 2022, 69, e17942.

23.   G. Li, T. Yan, H. Zhao, Dahuan Liu*, Effective removal of nitroimidazole antibiotics in aqueous solution by an aluminum-based metal-organic framework: Performance and mechanistic studies, J. Solid State Chem., 2023, 317, 123659.

24.    M. Chang, T. Yan, Y. Wei, J.-X. Wang*, Dahuan Liu*, J.-F. Chen, A metal-organic framework-based single-molecule SF6 trap for record SF6 capture, Chem. Mater., 2022, 34, 9134-9143.

25.    X. Wang, Y. Zhao, Y. Sun, Dahuan Liu*, Highly effective removal of ofloxacin from water with copper-doped ZIF-8, Molecules, 2022, 27, 4312.

26.    X. Zhao, C. Zhang, B. Liu*, H. Zhao, X. Gao, Y. Wang, Y. Zhang, Dahuan Liu*, C.-C. Wang*, Resource mining of stainless steel pickling wastewater to produce metal-organic frameworks, Resources, Conservation & Recycling, 2023, 188, 106647.

27.    M. Yang, M. Chang, T. Yan, Dahuan Liu*, A nickel-based metal-organic framework for efficient SF6/N2 separation with record SF6 uptake and SF6/N2 selectivity, Sep. Purif. Technol., 2022, 295, 121340.

28.    M. Chang†, F. Wang†, Y. Wei, Q. Yang, J.-X. Wang*, Dahuan Liu*, J. -F. Chen, Separation of CH4/N2 by an Ultra-Stable Metal-Organic Framework with the Highest Breakthrough Selectivity, AIChE J., 2022, 68, e17794.

29.    M. Chang†, T. Yan†, Y. Wei, J.- X. Wang*, Dahuan Liu*, J. -F. Chen, Enhancing CH4 Capture from Coalbed Methane through Tuning van der Waals Affinity within Isoreticular Al-Based MOFs, ACS App. Mater. Interfaces, 2022, 14, 25374−25384.

30.    H. Zhao, Y. Zhao, X. Zhao*, Dahuan Liu*, Introduction of alkyl and sulfonic groups in Ti-metal-organic framework for boosting removal of metformin hydrochloride, J. Mol. Struct., 2022, 1263, 133121.

31. X. Gu, G. Han, Q. Yang,Dahuan Liu*, Confinement-Unconfinement Transformation of ILs in IL@MOF Composite with Multiple Adsorption Sites for Efficient Water Capture and Release, Adv. Mater. Interfaces, 2022, 2102354.

32.  G. Li, H. Zhao, P. Guo, Dahuan Liu*, Effective removal of tinidazole by MIL-53(Al)-NDC metal-organic framework from aqueous solution, J. Solid State Chem., 2022, 310, 123066.

33.    P. Guo, Y. Chen, M. Chang, Y. Li, Q. Yang, Dahuan Liu*, A Stable Cu(I)-based Ultramicroporous NKMOF-8-Br with High CH4 Uptake for Efficient Separation of CH4/N2 Mixtures, J. Chem. Eng. Data, 2022, 67, 1654-1662.

34.    T. Wang, H. Zhao, X. Zhao*, Dahuan Liu*, One-step preparation of Ag0-MOF Composites for Effective Removal of Iodide from Water, J. Solid State Chem., 2022, 305, 122680.

35.  T. Yan, Dahuan Liu*, Q. Yang*, C. Zhong, Screening and Design of COF-Based Mixed-Matrix Membrane for CH4/N2 Separation, Chinese J. Chem. Eng., 2022, 42, 170-177.

36.    P. Guo, M. Chang, T. Yan, Y. Li, Dahuan Liu*, A pillared-layer metal-organic framework for efficient separation of C3H8/C2H6/CH4 in natural gas, Chinese J. Chem. Eng., 2022, 42, 10-16.

37.    M. Chang, Y. Wei, Dahuan Liu*, J.-X. Wang*, J.-F. Chen, A General Strategy for Instantaneous and Continuous Synthesis of Ultrasmall Metal-Organic Framework Nanoparticles, Angew. Chem. Int. Ed., 2021, 60, 26390–26396.

38.    G. Mercuri, M. Moroni, S. Galli*, G. Tuci, G. Giambastiani, T. Yan, Dahuan Liu*, A. Rossin*, Temperature-dependent nitrous oxide/carbon dioxide preferential adsorption in a thiazolium-functionalized NU-1000 Metal-Organic Framework, ACS App. Mater. Interfaces, 2021, 13, 58982–58993.

39.    Y. Zhao, H. Zhao, Dahuan Liu*, Selective adsorption and separation of o-xylene using an aluminum-based metal-organic framework, Ind. Eng. Chem. Res., 2021, 60, 17143–17149.

40.    M. Chang, J. Ren, Y. Wei, J.-X. Wang*, Q. Yang*, Dahuan Liu*, J.-F. Chen, A Robust Metal-Organic Framework with Guest Molecules Induced Splint-like Pore Confinement to Construct Propane-Trap for Propylene Purification, Sep. Purif. Technol., 2021, 279, 119656.

41.  Y. Li, T. Wang, Dahuan Liu*, Fabrication of ultrathin membranes using 2D-MOF nanosheets for tunable gas separation, Chem.-Asian J., 2021, 16, 3413-3418.

42. H. Zhao, Y. Zhao, Dahuan Liu*, pH- and H2S- Dual-Responsive Magnetic Metal-Organic Frameworks for Controlling Release of 5-Fluorouracil, ACS Applied Bio Materials, 2021, 4, 7103−7110.

43.    J. Ren, M. Chang, W. Zeng, Y. Xia, Dahuan Liu*, G. Maurin,* Q. Yang,* Computer-Aided Discovery of MOFs with Calixarene-Analogous Microenvironment for Exceptional SF6 Capture, Chem. Mater., 2021, 33, 5108–5114.

44.    C. Liu, Y. Liu, Z. Xiang,* Dahuan Liu*, Q. Yang,* Bimetallic MOF-derived sulfides with heterojunction interfaces synthesized for photocatalytic hydrogen evolution, Ind. Eng. Chem. Res., 2021, 60, 11439–11449.

45.    Y. Zhao, P. Liu, Y. Ying*, K. Wei, D. Zhao,Dahuan Liu*, Heating-driven assembly of covalent organic framework nanosheets for gas separation, J. Membr. Sci., 2021, 632, 119326.

46.  T. Wang, M. Chang, T. Yan, Y. Ying*, Q. Yang, Dahuan Liu*, Calcium-Based Metal−Organic Framework for Efficient Capture of Sulfur Hexafluoride at Low Concentrations, Ind. Eng. Chem. Res., 2021, 60, 5976−5983.

47.    W.-Q. Tang, Y.-J. Zhao, M. Xu, J.-Y. Xu, S.-S. Meng, Y.-D. Yin, Q.-H. Zhang, L. Gu, Da-Huan Liu* and Z.-Y. Gu*, Controlling the Stacking Modes of Metal-Organic Framework Nanosheets through Host-Guest Noncovalent Interactions, Angew. Chem. Int. Ed., 2021, 60, 6920-6925.

48.   G. Han, N. Yu, Dahuan Liu*, G. Yu*, X. Chen, C. Zhong*, Stepped Enhancement of CO2 Adsorption and Separation in IL-ZIF-IL Composites with Shell-Interlayer-Core Structure, AIChE J., 2021, 67(2), e17112.

49.  M. Chang, J. Ren, Q. Yang*, Dahuan Liu*, A robust calcium-based microporous metal-organic framework for efficient CH4/N2 separation, Chem. Eng. J., 2021, 408, 127294.

50.  T. Wang, H. Zhao, X. Zhao*, Q. Yang*, Dahuan Liu*, Silver Nanoparticles Prepared by One-Step Reaction via Reducibility of a Metal-Organic Framework to Remove the Toxic Bromine Ions. J. Chem. Eng. Data, 2021, 66, 535–543.


Awards

1. First Prize of Science and Technology Progress Award of China Petroleum and Chemical Industry Federation; 

2. Second Prize of the Beijing Science and Technology Award; 

3. First Prize of the Tianjin Science and Technology Award.

Patent

Honor Reward

Admissions Information

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